By R J Ferrier, R Blattner, O McDonald, R H Furneaux, P C Tyler, R H Wightman, J M Gardiner, R A Field, K P R Kartha, D M G Tilbrook, John O Hoberg
Carbohydrate Chemistry offers overview assurance of all guides suitable to the chemistry of monosaccharides and oligosaccharides in a given yr. the volume of study during this box showing within the natural chemical literature is expanding as a result better value of the topic, in particular in components of medicinal chemistry and biology. In no a part of the sphere is that this extra obvious than within the synthesis of oligosaccharides required by way of scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well tested, for instance, by way of the coaching of particular carbohydrate- dependent antigens, particularly cancer-specific oligosaccharides and glycoconjugates. insurance of themes resembling nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot examine of relevance to organic and medicinal chemistry. every one quantity of the sequence brings jointly references to all released paintings in given components of the topic and serves as a finished database for the energetic study chemist professional Periodical stories offer systematic and specified evaluate insurance in significant components of chemical examine. Compiled through groups of prime gurus within the appropriate topic components, the sequence creates a distinct carrier for the lively study chemist, with usual, in-depth money owed of growth specifically fields of chemistry. topic insurance inside of assorted volumes of a given name is identical and ebook is on an annual or biennial foundation.
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N. L. P. Serebryakov, Tetrahedron, 1999,55, 3665. E. Moyroud and P. Strazewski, Tetrahedron, 1999,55, 1277. A. Trifonova, A. Foldesi, Z. Dinya and J. Chattopadhyaya, Tetrahedron, 1999, 55,4747. M. D. A. O'Doherty, J. Org. , 1999,64,2982. 14 Carbohydrate Chemistry 11 12 13 14 15 16 17 18 H. Siendt, T. Tschamber and J. , 1999,40, 5191. H. Hajk6, A. Liptak and V. Pozsgay, Carbohydr. , 1999,321, 116. H. E. Stiitz, Carbohydr. , 1999,319, 55. M. Frank, R. Miethchen aand D. , 1999,318,167. M. Adinolfi, G.
Bernardinelli, J. Carbohydr. , 1999, 18, 343. E. M. Paton, Carbohydr. , 1999,321,24. O. E. M. Paton, Carbohydr. , 1999,322, 1 . S. Jarosz, S. Skora, A. Stefanowicz, M. Mach and J. Frelek, J. Carbohydr. , 1999,18,961. S. Jarosz, M. Mach and S . Skora, Synlett, 1999, 313. A. Marco, M. Carda, E. Falomir, C. Palomo, M. A. Ortiz and A. , 1999,40, 1065. M. Carda, E. Falomir, J. Murga, F. A. , 1999,40,6845. Z. Hricoviniova-Bilikovaand L. Petrus, Carbohydr. , 1999,320, 3 1. M. A. Lopez-Sastre, M. R. Patiiio Molina, T.
37Reaction of osulose 58 with phosphorane 61, synthesized from 2-ethyl-1,3-propanediol in four steps, including enzyme-catalysed, desymmetrizing acetylation, furnished 60, after saturation of the double bond. Ph CPh CH20H 55X=O 56X= N O H 57 58 R = CHO 59 R = CH&H&N 60 R = CH~CH~CHCH~OAC I Et yH20Bn &y Y 4 40 BnO 62 63 X,Y = _/Co2Et 64X= -CQEt,y=H 6 5 X = ,/\Jco2E‘,Y=H OAc Compound 63 and similar em-glycals were prepared by conventional Wittig alkylidenation of protected hexono-1,5-1actones. 40 Acetylenic C-glycosides, for example compound 68,have been obtained by reaction of a sugar lactone with a carbohydrate-derived lithium acetylide (see Vol.